A comprehensive description of the geology of Mount Gibraltar is found in The Gib (2007), a free e-book which is linked to from this webpage. Contrary to popular belief, there is no evidence that Mount Gibraltar is the core of an erupting volcano (Carr, P., 2007), but the result of an intrusion, uplift, and erosion over millennia.
Injection of a syenitic melt near the bottom of Hawkesbury Sandstone and overlying Wianamatta Shale created the pressure for this uplift. The microsyenite exposed today is a result of erosion exposing it over millions of years.
The Gib has an interesting mix of plant community types because of the presence of microsyenite, sandstone and shale.